E-ISSN 2705-3954 | ISSN 0794-4756
 

Original Research 


Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution

Akindele Oyetunde Okewale, Judith Umukoro, Ayodeji Adebayo.

Abstract
This work studies the adsorption mechanism of pumpkin pod extract as corrosion inhibitor and its parameters of thermodynamics in carbon dioxide saturated brine environment on carbon steel metal surface. Method of loss in weight was utilized in establishing the rate of oxidation. Appropriate thermodynamics models were deployed to know the Gibbs free change of energy using four adsorption isotherms models. The study on its adsorption mechanism revealed that the experimental data is suitable for the Langmuir, Freundlich, Temkin, and El – Awady but Langmuir isotherm provided the superlative fit. Free energy of Gibb’s adsorption was less than -20KJ/mol maximum limit and negative for Langmuir and Freundlich isotherms except for Temkin whose threshold value is higher than -20KJ/mol, and El – Awady’s isotherm model that gave positive values for the ∆G. The adsorption of pumpkin pod extract on carbon steel in carbon dioxide saturated saline environment is feasible, spontaneous, and occurred by physisorption in accordance with Langmuir isotherm model.

Key words: Gibbs free energy, Corrosion rate, Pumpkin pod, Carbon steel, Corrosion thermodynamics, Adsorption isotherms


 
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How to Cite this Article
Pubmed Style

Okewale AO, Umukoro J, Adebayo A, . Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution. NJE. 2021; 28(3): 41-49.


Web Style

Okewale AO, Umukoro J, Adebayo A, . Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution. https://www.njeabu.com.ng/?mno=56744 [Access: April 05, 2022].


AMA (American Medical Association) Style

Okewale AO, Umukoro J, Adebayo A, . Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution. NJE. 2021; 28(3): 41-49.



Vancouver/ICMJE Style

Okewale AO, Umukoro J, Adebayo A, . Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution. NJE. (2021), [cited April 05, 2022]; 28(3): 41-49.



Harvard Style

Okewale, A. O., Umukoro, J., Adebayo, A. & (2021) Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution. NJE, 28 (3), 41-49.



Turabian Style

Okewale, Akindele Oyetunde, Judith Umukoro, Ayodeji Adebayo, and . 2021. Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution. Nigerian Journal of Engineering, 28 (3), 41-49.



Chicago Style

Okewale, Akindele Oyetunde, Judith Umukoro, Ayodeji Adebayo, and . "Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution." Nigerian Journal of Engineering 28 (2021), 41-49.



MLA (The Modern Language Association) Style

Okewale, Akindele Oyetunde, Judith Umukoro, Ayodeji Adebayo, and . "Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution." Nigerian Journal of Engineering 28.3 (2021), 41-49. Print.



APA (American Psychological Association) Style

Okewale, A. O., Umukoro, J., Adebayo, A. & (2021) Adsorption and Thermodynamics Parameters of Carbon Steel Corrosion Inhibition in Saturated CO2 Saline Solution. Nigerian Journal of Engineering, 28 (3), 41-49.